Citation: HOU Xiaohuai, Masao Kaneko, Akira Yamada. PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*[J]. Chinese Journal of Polymer Science, ;1984, 2(2): 151-158. shu

PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*

Received Date: 24 February 1984

Polymeric pendant Ru(bpy)32+ complexes were prepared from homopolymer and copolymers of 4-methyl-4'-vinyl-2,2'-bipyridine (Vbpy). Vbpy was prepared from 4-methylpyridine. The comonomers were styrene (St), acrylic acid (AA), N-vinylpyrrolidone (Pyr), 4-vinylpyridine (Vpy), methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA), acrylonitrile (AN) and N-ethyl-4-vinylpyridium bromide (EQ-Vpy). The fraction of the pendant Ru(bpy)32+ repeating unit in the polymeric complex was 0.022 to 0.052. Absorption maximum,molar extinction coefficient,emission maximum and relative emission intensity of the polymeric complexes were studied.
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