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Citation: Fang Yan. Electrochemical Behavior of Li/Zeolotes Cells[J]. Chinese Journal of Applied Chemistry, ;1995, 12(2): 24-28. shu

Electrochemical Behavior of Li/Zeolotes Cells

Fang Yan

Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008

Received Date: 31 July 1994
Revised Date: 31 October 1994

The discharge and cyclic voltammetry behavior of a variety of zeolites as cathode of lithium secondary cell have been studied by coulometric titration,infrared absorption spectrosoepy and X-ray diffractometry. It was found that in the course of discharge lithium is electrochemically intercalated into compound at discharge depth x < 3.4mol. The intercala-tion free energy of Li into NaA zeolite was found to be -231kJ/mol (25℃). The chemical diffusion coefficient of lithium in LixNaA (x=0.17~0.69) was determined to be about 1×10^-9~1×10^-10cm²/s at room temperature.
- lithium-zeolite cell,
- intercalation,
- electrochemical behavior
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