Citation: Qi FANG, Hong LEI, Wen XU. Towards Single-component Molecular Conductor[Ni(dmit)₂] by Charge Disproportionation:2[Ni(dmit)₂]^-0.5→[Ni(dmit)₂]+[Ni(dmit)₂]^-[J]. Chinese Chemical Letters, ;2003, 14(11): 1109-1112. shu

Towards Single-component Molecular Conductor[Ni(dmit)₂] by Charge Disproportionation:2[Ni(dmit)₂]^-0.5→[Ni(dmit)₂]+[Ni(dmit)₂]^-

Qi FANG ^1, ,
Hong LEI ² ,
Wen XU ¹

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
School of Information Science and Engineering, Shandong University, Jinan 250100

Received Date: 28 October 2002

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20172034), Foundation for University Key Teacher by Ministry of Education, and the grant for the State Key Program of China.

A new method of synthesizing single-component molecular conductor[Ni(dmit)₂] by the reaction 2(Me₄N)[Ni(dmit)₂]₂→[Ni(dmit)₂]+(Me₄N)[Ni(dmit)₂] is reported.[Ni(dmit)₂] exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity.
- Single-component molecular conductors,
- conductivity,
- charge disproportionation
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