Citation: Xiao Zhi GUO, Xiao Mei WANG, Yu Kou DU, Nan Ping HUA, Ming SHEN, Wan Li JIANG, Ping YANG. Synthesis and Nonlinear Optical Properties of New Quadrupolar Chromophores[J]. Chinese Chemical Letters, ;2005, 16(5): 597-600. shu

Synthesis and Nonlinear Optical Properties of New Quadrupolar Chromophores

1.
Department of Chemistry, Soochow University, Suzhou 215006;
2.
College of Material Science and Engineering, Soochow University, Suzhou 215021;
3.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100

Received Date: 9 May 2004

Fund Project: This work was supported by the NNSFC(No. 50273024), the Natural Foundation of Jiangsu Province (No. BK2002041 and BK2003031) and the Foundation of Jiangsu Province Education Committee (No. 02KJB430001 and 03KJB150115).

Two new symmetric chromophores:2, 8-bis-[(2-4'-ethoxy phenyl-5-4'-styryl)-1, 3, 4-oxadiazole] didibenzothiophene (abbreviated as SO-G₁) and 2, 8-bis-[(2-4'-ethoxy phenyl-5-4'-styryl)-1, 3, 4-oxadiazole]-N-ethyl carbazole (abbreviated as NO-G₁) have been synthesized and characterized. Both chromophores exhibit strong two-photon absorption (TPA) with the cross-sections of 2.99×10^-48 and 3.48×10^-48 cm⁴·s·photon^-1 in THF and large up-conversion emission, when pumped by Ti:sapphire femto-second laser at 720 nm.
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