Citation: Yong Qiang MA, Xiao CHEN, Jing LI, Qing Lan XIE, Hong Gen WANG. Synthesis and Reaction of[MnRe(CO)₆(μ-SH)(μ-SC(H)PPr₃ⁱ)(PPh₃)][J]. Chinese Chemical Letters, ;2003, 14(4): 413-416. shu

Synthesis and Reaction of[MnRe(CO)₆(μ-SH)(μ-SC(H)PPr₃ⁱ)(PPh₃)]

State Key Laboratary of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071

Received Date: 15 July 2002

Fund Project: We thank the National Natural Science Foundation of China (No. 29672018) for financial support.

The synthesis, the crystal structure and the reaction of the hetero-binuclear complex[MnRe(CO)₆(μ-SH)(μ-SC(H)PPr₃ⁱ)(PPh₃)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)₃ and Re(CO)₃ were bridged by SH and SC(H)PPr₃ⁱ. The title complexes can react with BuⁿLi and RX forming complexes MnRe(CO)₆(μ-SR)(μ-SC(H)PPr₃ⁱ)(PPh₃) (R=Me, CH₂CH=CH₂, SnBu₃ⁿ).
- Hetero-binuclear complexes,
- synthesis,
- reaction,
- crystal structure
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