Citation: HUANG Jiaxian, CHEN Guohua, EDDY TIJSMA, LEEN VAN DER DOES, ADRIAAN BANTJES. INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)[J]. Chinese Journal of Polymer Science, ;1990, 8(3): 197-203. shu

INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)

HUANG Jiaxian ^{*，陈国华，EDDYTIJSMA，LEENVANDERDOES，ADRIAANBANTJES} ,
CHEN Guohua ,
EDDY TIJSMA ,
LEEN VAN DER DOES ,
ADRIAAN BANTJES

Received Date: 15 December 1989

Bulk polymerization of vinylene carbonate using t-butylperoxypivalate at 40℃ gave colourless, high molecular weight poly(vinylene carbonate) (PVCA). Solutions of PVCA in acetone and DMF are not stable at 25℃ and this degradation was studied. From measurements in DMF with unfractionated PVCA a Mark-Houwink equation was obtained:[η](dl g -1)=1.63×10-4M0.736w
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