Citation: Xing Xian ZHANG, Wei Dong LI, Ben Can TANG. Mukaiyama Aldol Reaction of 1, 2-Bis(trimethylsiloxy) Cyclobutene Catalyzed by Magnesium(Ⅱ) Iodide[J]. Chinese Chemical Letters, ;2003, 14(3): 225-228. shu

Mukaiyama Aldol Reaction of 1, 2-Bis(trimethylsiloxy) Cyclobutene Catalyzed by Magnesium(Ⅱ) Iodide

National Laboratory of Applied Organic Chemistry & Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 15 April 2002

Fund Project: We are grateful for the financial supports from the National Outstanding Youth Fund (No. 29925204), the Foundation for University Key Teacher by the Ministry of Education of China, and a Visiting Fund of the National Laboratory of Applied Organic Chemistry.

Efficient Mukaiyama-type aldol reaction of 1, 2-bis(trimethylsiloxy)cyclobutene with aromatic aldehydes catalyzed by MgI₂ is reported. The resulting succinoylation product of aldehyde was converted into the synthetic useful γ-lactone and butenolide derivatives.
- Mukaiyama aldol reaction,
- 1,2-bis(trimethylsiloxy)cyclobutene,
- magnesium iodide
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