Citation: Hui ZHANG, Cai Fei ZHU, Li LI, Wei ZOU, Yong Qing HUANG, Jing Xing GAO. Synthesis and CD Spectra of Chiral Molybdenum-fullerenyl Complexes with Pineno-bipyridine Ligands[J]. Chinese Chemical Letters, ;2004, 15(12): 1411-1414. shu

Synthesis and CD Spectra of Chiral Molybdenum-fullerenyl Complexes with Pineno-bipyridine Ligands

Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005

Received Date: 22 October 2003

Fund Project: The supports in this work from the NNSFC (20171037, 20373056), the Provincial NSF of Fujian Province (2002F016, C0020001) are greatly appreciated.

The synthesis and characterization of two chiral fullerene complexes (+)₄₃₀^CD-[Mo(η²-C₆₀)(CO)₃(L^RR)] 1 and (-)₄₃₀^CD-[Mo(η²-C₆₀)(CO)₃(L^SS)] 2 were described. The CD spectra of 1 and 2 in the visible range show weak Cotton effects, which are approximately of mirror image, indicating that the appended pineno-groups with opposite chirality in bipyridines can perturb the fullerene chromophores through the molybdenum centers and lead to induced CD effects.
- Mo complexes,
- chirality,
- bipyridine,
- fullerenes,
- CD spectra
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