Citation: Shu Qing LIU, Ji Qing XU, Hao Ran SUN. Novel Properties of Supramolecular Complexes Formed by Pairing Cationic Porphyrin and Anionic Metal-Oxo Cluster[J]. Chinese Chemical Letters, ;2000, 11(9): 831-834.
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MTBPyP (meso-tetrakis (4-N-benzylpyridyl) porphyrin, M=H2, Zn) bearing positive charge has been shown to associate with SiW12O404- in water solution.The spectral evolution and Job's plots analyses reveal that the relatively stable aggregates contain equal numbers of MTBPyP4+ and SiW12O404-.
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