Citation: Shu Qing LIU, Ji Qing XU, Hao Ran SUN. Novel Properties of Supramolecular Complexes Formed by Pairing Cationic Porphyrin and Anionic Metal-Oxo Cluster[J]. Chinese Chemical Letters, ;2000, 11(9): 831-834. shu

Novel Properties of Supramolecular Complexes Formed by Pairing Cationic Porphyrin and Anionic Metal-Oxo Cluster

Department of Chemistry, Jilin University, Changchun 130023

Received Date: 6 March 2000

Fund Project: This work was supported by the National Natural Science Foundation of China under grant No.29733090 and No.29803003 and the Research Found for the Doctoral Program of Higher Education.

MTBPyP (meso-tetrakis (4-N-benzylpyridyl) porphyrin, M=H₂, Zn) bearing positive charge has been shown to associate with SiW₁₂O₄₀^4- in water solution.The spectral evolution and Job's plots analyses reveal that the relatively stable aggregates contain equal numbers of MTBPyP⁴⁺ and SiW₁₂O₄₀^4-.
- Cationic porphyrin,
- anionic metal-oxo cluster,
- ion pair supramolecular complex
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