Citation: Hui Mou LUO, Yi Qun LI, Wen Jie ZHENG. A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes[J]. Chinese Chemical Letters, ;2005, 16(7): 906-908. shu

A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes

Department of Chemistry, Jinan University, Guangzhou 510632

Received Date: 16 August 2004

Fund Project: The project was supported by the National Natural Science Foundation of China (No 20272018), the Guangdong Natural Science Foundation (No 021166, 04010458) and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of China.

A variety of carbonyl compounds can be converted into oximes efficiently and conveniently in a novel ionic liquid/water bi-phasic system in the presence of sodium bicarbonate at ambient temperature. The ionic liquid 1-butyl-3-methyl imidazolium hexafluorophosphate[bmim]PF₆ is immiscible with water or diethyl ether and can be easily recycled for reuse without noticeable droping in activity after separation of the products. The protocol is rapid, the yields are excellent, the method is simple and the ionic liquid can be reused.
- Oximes,
- synthesis,
- ionic liquid,
- bi-phasic system
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