Citation: QIU Kunyuan, LU Zhihua, TANG Aijun, FENG Xinde. VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS[J]. Chinese Journal of Polymer Science, ;1992, 10(4): 366-371. shu

VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS

Received Date: 6 January 1992

The polymerization of acrylamide (AAM)in H2O/DMF or in H2O/CH3CN mixed solvent initiated with ceric ion (Ce4+ )/N-(substituted phenyl)-acetamide systems have been studied. The redox polymerization was revealed by the low value of overall activation energy (Eα) of AAM polymerization using ceric ion/N-(substituted phenyl) acetamide system as an initiator. The end group of polymer formed was detected by IR spectrum analysis method, it revealed the presence of N-(m-acetoxy-methylphenyl) acetamide (m-AAe) moiety end group in the polymer obtained with ceric ion/m-AAe initiation system.
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