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Citation: Ding Liming, Lin Yunqing, Liang Hongze, Wang Dongmei, Wang Fosong. Studies on Novel Solid Polymer Electrolytes(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;1995, 12(4): 96-98. shu

Studies on Novel Solid Polymer Electrolytes(Ⅱ)

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 31 October 1994
Revised Date: 9 January 1995

The comblike polymer based on methyl vinyl ether/maleic anhydride copolymer with oligo-oxyethylene chains (BM350) dissolved NaClO₄,forming a homogeneous amor-phous polymer electrolyte. The T_g of the polymer were found to be increased with salt addi-tion. The BM350/NaClO₄ complex at a [Na]/[EO] ratio of 0.25 exhibited ionic conductivityof 1.03 × 10^-4S/cm at 25℃. The conductivity of the polymer electrolytes obeys the VTF e-quation and has been discussed in terms of the changes in confugurations.
- comblike polymer,
- NaClO₄-complex,
- solid electrolyte,
- ionic conductivity
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