Citation: Xiao Ying HUANG, Hong Bing CHEN, Shao Fang LU. SYNTHESIS AND CRYSTAL STRUCTURE OF Mo₂S(μ-S)₂[S₂CNC₄H₈]₂[J]. Chinese Chemical Letters, ;1993, 4(11): 1033-1034. shu

SYNTHESIS AND CRYSTAL STRUCTURE OF Mo₂S(μ-S)₂[S₂CNC₄H₈]₂

State Key laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou 350002

Received Date: 15 April 1993

Mo₂OS (μ-S) ₂[S₂CNC₄H₈]₂, Mr=612.61, triclinic, P1, a=8.666 (2)Å, b=17.366 (6)Å, c=6.708 (1)Å, α=98.29 (2)°, β=97.27 (2)°, γ=79.36 (2)°, V=976.5 (5)Å³, Z=2, Dc=2.03g/cm³, MoKα (λ=0.71069 (?)), μ=19.75cm^-1, F (000)=588, Final R=0.064, Rw=0.073 for 1517 unique intensity data (I>3σ(I)). The binuclear unit of[Mo₂OS₃] has a new asymmetrically terminal coordinated configuration with Mo-Mo distance of 2.807(3)Å.
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