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Citation: Liu Yumin, Zhu Kaizheng, Liu Shetian, Yie Xingkai, Wu Yue. CoCuAl Hydrotalcite-like Compounds: Synthesis and Use in the Catalytic Oxidation of p-Cresol Ⅱ.Catalytic Oxidation of p-Cresol[J]. Chinese Journal of Applied Chemistry, ;1998, 15(2): 18-22. shu

CoCuAl Hydrotalcite-like Compounds: Synthesis and Use in the Catalytic Oxidation of p-Cresol Ⅱ.Catalytic Oxidation of p-Cresol

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 24 September 1997
Revised Date: 10 December 1997

The oxidation of p-cresol using CoCuAl hydrotalcite like compounds(HTLc) has been investigated. The calcinated HTLcs were found to have a higher activity than the uncalcinated ones, as well as the simple mixed oxides. The products from calcination at 450℃ with Co:Cu:Al=3:1:1 showed an optimum activity, giving 98.4% yield of p-hydroxy benzaldehyde. A possible mechanism has been proposed, assuming that both Co²⁺ and Co³⁺ in the catalysts with spinel structure act as an active center in the reaction.
- CoCuAlCO₃,
- catalytic oxidation,
- p-cresol,
- p-hydroxybenzaldethyde,
- reaction mechanism
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