Citation: Xian Xian LIU, Yan Song ZHENG, Wan Ling MO. An Inherent Chiral Calix[4]arene Bearing Chiral Groups without Forming Sub-ring[J]. Chinese Chemical Letters, ;2006, 17(9): 1169-1172. shu

An Inherent Chiral Calix[4]arene Bearing Chiral Groups without Forming Sub-ring

1.
Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074;
2.
Department of Chemistry, Guilin Normal College, Guilin 541001

Received Date: 15 March 2006

Fund Project: The authors are grateful for the financial support of the National Natural Science Foundation of China (No. 20072007).

The NMR spectra revealed that the calixarene frame of 1, 3-disubstituted calix[4]arenes bearing optically active groups is asymmetric, even without the formation of a sub-ring. This inherent chirality arises from the interaction of the two chiral groups, which hinder the substituents' free rotation. Thus, these chiral calix[4]arenes display good chiral recognition ability.
- Calixarene,
- inherent chirality,
- chiral recognition
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