Citation: Ruo Jun SUN, Hui JIANG, Zhi Zhen HUANG. Novel Stereoselective Synthesis of (E)-α,β-Unsaturated Esters by the Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction from Phosphonium and Arsonium Salt[J]. Chinese Chemical Letters, ;2003, 14(3): 243-244. shu

Novel Stereoselective Synthesis of (E)-α,β-Unsaturated Esters by the Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction from Phosphonium and Arsonium Salt

Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 15 April 2002

Fund Project: We thank the National Natural Science Foundation of China for financial support of the project 29972036 and the Foundation of Educational Ministry for the Scholars Returning from Abroad.

Phosphonium or arsonium salt 1 can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction with alcohol 2 in the presence of sodium hydroxide and manganese dioxide, which affords a general simplified method for the stereoselective synthesis of (E)-α,β-unsaturated esters 3.
- Phosphonium salt,
- arsonium salt,
- alcohol,
- ylide,
- α,β-unsaturated esters,
- Wittig reaction,
- tadem reaction,
- synthesis
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