Citation: Ying HAN, Zheng Fa CHI, Yao Zeng HUANG. METALLIC GALLIUM-PROMOTED REFORMATSKY-TYPE REACTION[J]. Chinese Chemical Letters, ;1996, 7(8): 713-716. shu

METALLIC GALLIUM-PROMOTED REFORMATSKY-TYPE REACTION

a Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry Chinese Academy of Sciences, Fenglin Lu 354, Shanghai 200032;
b Department of Chemistry, Chengdu Normal College, Chengdu 611930

Received Date: 9 January 1996

Fund Project: We thank Prof Dai Li-xin for kind help and the National Natural Science Foundation of China and Academia Sinica for financial support.

Gallium-mediated Reformatsky-type reactions gave ethyl esters of β-hydroxy acids, and ethyl esters of-α-vinyl-β-hydroxy acids in excellent yields and very high regioselectivity.
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