Citation:
Zhi Zhou YUE, Yuan Chao LI. A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O-(p-methoxybenzyl)-D-myo-inositol[J]. Chinese Chemical Letters,
;2005, 16(2): 171-174.
-
Highly efficient synthesis of the entitled compound was achieved from a readily available myo-inositol derivative. The key step involved a desymmetrization with (+)-camphor dimethyl ketal to give two diastereomers. The two diastereomers could be used to synthesize the same compound by changing the orders to introduce the protective groups.
-
Keywords:
- Inositol,
- (+)-camphor dimethyl ketal,
- desymmetrization.
-
-
-
-
[1]
Yujia Shi , Yan Qiao , Pengfei Xie , Miaomiao Tian , Xingwei Li , Junbiao Chang , Bingxian Liu . Rhodium-catalyzed enantioselective in situ C(sp3)−H heteroarylation by a desymmetrization approach. Chinese Chemical Letters, 2024, 35(10): 109544-. doi: 10.1016/j.cclet.2024.109544
-
[1]
Metrics
- PDF Downloads(1)
- Abstract views(516)
- HTML views(7)