Citation: XU Hui, CAO Xinyu, LI Ze, CAO Ming, DAI Daorong, XIE Ping, ZHANG Rongben. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. Chinese Journal of Polymer Science, ;1998, 16(3): 253-260. shu

A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*

Received Date: 4 October 1997

A novel supramolecular polysiloxane clathrate, POS/C, has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA ) , one kindof Schiff base liquid crystal molecule, within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM), differ-ential scanning calorimetry (DSC), infrared spectroscopy (IR), atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.
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