Citation: Jun Fan, Hong-liang Jiang, Kang-jie Zhu. EFFECT OF SUBSTITUTION POSITION OF HYDROXY GROUP AT BENZOIC ACID ON THE LUMINESCENT AND DEGRADATION PROPERTIES OF POLY[DI(CARBOXYPHENYL) SUCCINATE-co-SEBACIC ANHYDRIDE]S[J]. Chinese Journal of Polymer Science, ;2007, 25(3): 253-261. shu

EFFECT OF SUBSTITUTION POSITION OF HYDROXY GROUP AT BENZOIC ACID ON THE LUMINESCENT AND DEGRADATION PROPERTIES OF POLY[DI(CARBOXYPHENYL) SUCCINATE-co-SEBACIC ANHYDRIDE]S

Received Date: 12 April 2006
Revised Date: 14 June 2006

In this work, two new diacids, di(m-carboxyphenyl) succinate (m-dCPS) and di(o-carboxyphenyl) succinate (o-dCPS), were synthesized by reaction of m-, o-hydroxy benzoic acid with succinic chloride, respectively. Their corresponding copolymers with sebacic acid (SA), P(m-dCPS׃SA) and P(o-dCPS׃SA), were prepared by melt copolycondensation and characterized by NMR, UV and DSC methods. Compared with inherently fluorescent poly[di(p-carboxyphenyl) succinate-co-sebacic anhydride] (P(p-dCPS׃SA)), P(m-dCPS׃SA) and P(o-dCPS׃SA) displayed different luminescent properties. P(m-dCPS׃SA) could emit fluorescence under the excitation of both visible and UV light, while P(o-dCPS׃SA) could only emit fluorescence when excited with UV light. Degradation rate of the two new copolyanhydrides increased with the increase of SA fraction in the copolymers. In addition, P(o-dCPS׃SA) degraded more rapidly than P(m-dCPS׃SA) with the same composition. Typical surface-degradation characteristics of these copolyanhydrides were observed.
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