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Wei Chun FENG, Dung WANG. SHARPLESS ASYMMETRIC EPOXIDATION OF HEPTENYLPHENYLMETHYLSILANOL[J]. Chinese Chemical Letters,
;1995, 6(8): 647-650.
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The Sharpless asymmetric epoxidation of 1 was carried out to give the (1S, 2S)-4 in 33% yield, which was protodesilylated, giving (-)-5 with 50% ee.The steric effect of phenyl group on silicon upon the rate and ee of the reaction was observed.The possibility of kinetic resolution of racemic silanol under the Sharpless reaction condition was examined.
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