Citation: Wei Yuan HUANG, Yuan XIE. The Reaction of Sodium Perfluoroalkanesulfinate with PCl₃[J]. Chinese Chemical Letters, ;1990, 1(1): 27-28. shu

The Reaction of Sodium Perfluoroalkanesulfinate with PCl₃

Wei Yuan HUANG ,
Yuan XIE

Shanghai Institute of Organic Chemistry Chinese Academy of Sciences 345 Lingling Lu Shanghai 200032 China

Received Date: 25 January 1990

The reaction between sodium perfluoroalkanesulfinate(1)(Rf=a, Cl(CF₂)₄;b, Cl(CF₂)6;c, Cl(CF₂)₈;d, n-C₆F₁₃;e, n-C₈F₁₇;f, H(CF₂)₄OCF₂CF₂)andphosphorus trichloride in acetonitrile at 0℃ resulted in the formation of anunstable intermediate, which was hydrolysed directly with aqueous sodium hydro-xide solution to give the corresponding perfluorocarboxylic acid in good yield.
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