Citation: Zhi Qiang ZHANG, Shu Mei LIU, Zheng Hua TIAN. INVESTIGATION ON THE NEW SYNTHETIC REACTIONS AND MECHANISMS OF SUBSTITUTED DIPHENYL ETHEPS[J]. Chinese Chemical Letters, ;1991, 3(9): 687-688. shu

INVESTIGATION ON THE NEW SYNTHETIC REACTIONS AND MECHANISMS OF SUBSTITUTED DIPHENYL ETHEPS

Anshan Institute of Iron & Steel Technology Anshan 114002

Received Date: 1 July 1991

In the presence of alkali nitrite and carbonate, some nitrobenzenes substituted by strongly electron withdrawing group undergo a self condensation in an aprotic polar sotvent to give symmetrical disubstituted diphenyl ethers in good yields.A possible mechanism is discussed, the nucteophilic aromatic substitution S_NAr and S_RMAr may occur simultaneously.
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