Citation:
Tie Jun WANG, Ping CHEN, Xiu Jie HU, Shu Yun ZHOU. Sterically Stabilized Poly(3,4-ethylenedioxythiophene) Colloidal Dispersions Doped with Different Sulfonic Acids[J]. Chinese Chemical Letters,
;2006, 17(10): 1391-1393.
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The preparation of sterically stabilized poly(3, 4-ethylenedioxythiophene)(PEDOT)colloidal dispersions doped with different sulfonic acids is described. Three different sulfonic acids, i.e., p-toluenesulfonic acid, β-naphthalenesuffonic acid and D-camphor-10-sulfonic acid are used, facilitating the preparation of sterically stable PEDOT colloidal particles. The influences of the dopants and concentration of polymeric stabilizer on the yields, morphologies and electrical properties of the resultant colloidal particles were investigated. The colloidal particles with the size ranging from 172 to 334 nm have been obtained in good yields. The compressed pellet conductivity was as high as 4.5 Scm-1.
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Keywords:
- PEDOT,
- sulfonic acid,
- colloidal particles,
- polymeric stabilizer,
- conductivity
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