Citation: Chun Hua GE, Xiang Dong ZHANG, Wei GUAN, Qi Tao LIU, Zhan YU, Li Yan LIU. Supramolecular Architecture from the Self-assembly of One-dimensionalCoordination Polymers and Hydrogen Bonds[J]. Chinese Chemical Letters, ;2004, 15(2): 183-186. shu

Supramolecular Architecture from the Self-assembly of One-dimensionalCoordination Polymers and Hydrogen Bonds

1.
Institute of Chemical Science & Engineering, Liaoning University, Shenyang 110036;
2.
Faculty of Chemistry, Northeast Normal University, Changchun 130024;
3.
Department of Environmental Science, Liaoning University, Shenyang 110036

Received Date: 20 January 2003

Fund Project: This project is supported by the Natural Science Foundation of Education Bureau of Liaoning Province, China (No. 20021005).

The novel one-dimensional coordination polymer {[Cu(L)₂(H₂O)]·2BF₄·6H₂O}_∞[1, L=1, 2-bis(4-pyridinecarboxamido)ethane] was synthesized as single crystals and characterized by means of X-ray diffraction analysis, elemental analysis, IR spectroscopy and TG measurement. Structure 1 consists of looped chains. In addition, linked by hydrogen bonds, the one-dimensional chains were transformed into three-dimensional framework, which shows channels filled with anions and uncoordinated water molecules.
- Crystallization,
- coordination polymer,
- supramolecular chemistry
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