Citation: Zheng Chang XIONG, Lu Ling WU, Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters, ;2004, 15(1): 35-36. shu

Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction

1.
Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou 310028;
2.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 3 January 2003

The palladium catalyzed hydrostannation of 1-alkenylphosphonates gives the (E)-α-stannyl 1-alkenylphosphonates 2 stereospecifically. Compounds 2 can occur Stille coupling reaction to afford α, β-disubstituted vinylphosphonates with the retention of the configuration.
- 1-Alkenylphosphonate,
- hydrostannation,
- Stille reaction
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