Citation: Chu Chi TANG, You Ming WANG, Zheng Jie HE. Studies on Chiral Thiophosphoric Acids and Their Derivatives 15.The Asymmetric Cyclizations of L-prolinol with (Thio) phosphoro(-no) dichlorides[J]. Chinese Chemical Letters, ;1997, 8(2): 97-98. shu

Studies on Chiral Thiophosphoric Acids and Their Derivatives 15.The Asymmetric Cyclizations of L-prolinol with (Thio) phosphoro(-no) dichlorides

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 23 October 1996

Fund Project: This project was supported by National Natural Science Foundation of China.

The cyclizations of L-(+)-prolinol 1 derived from L-proline with (thio) phosphoro(-no) dichlorides 2 give 1,2,3-azaphosphaoxabicyclo[3.3.0]octanes 3 consisting of unequal amounts of diastereoisomers,eight pairs of which have been successfully separated by silica gel column chromatography or recrystallization.
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