Citation: Ye Gao YIN, Kung Kai CHEUNG, Wing Tak WONG. Supramolecular Metal Complex with Ferrocene-conjugated Macrocyclic Triaza Crown Ether as Ligand and Its Electrochemical Property[J]. Chinese Chemical Letters, ;1998, 9(3): 269-272. shu

Supramolecular Metal Complex with Ferrocene-conjugated Macrocyclic Triaza Crown Ether as Ligand and Its Electrochemical Property

a Department of Chemistry, Jingzhou Teachers College, Hubei. 434100;
b Department of Chemistry, The University of Hong Kong

Received Date: 27 October 1997

A tetranuclear complex[CO(Ⅲ)₂(L)₂(AcO)₂(OH)](AcO)(2I)4H₂O (L=N-ferrocenyl-methyl-1, 4, 7-triaza-cyclononane) was prepared from ligand L HI and its crystal structure was determined. The crystal exists in P2₁/a space group and its cell parameters are α=14.285(3)Å, b=19.888(3)Å, c=19.133(3)Å; β=109.12(2)°; V=5135.8Å³; Z=4. Electrochemical investigation reveals that the oxidation potential of ferrocenyl group in 1 has a 0.11V-positive-shift from that of the ferrocenyl group in L. HI.
- supermolecule,
- ferrocene,
- host-guest,
- electronic interaction
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