Citation: Bao Xue ZHOU, Shu Qin JIANG, Ding ZHOU, Yu Ting ZHAO. Preparation and Thermal Decomposition of [Cr (salen) (H₂O)₂] Cl[J]. Chinese Chemical Letters, ;1999, 10(5): 429-432. shu

Preparation and Thermal Decomposition of [Cr (salen) (H₂O)₂] Cl

1.
Department of Natural Science, Harbin Institute of Technology, Weihai Campus, Weihai, Shandong 264209;
2.
Department of Chemistry, Shandong University, Jinan 250100

Received Date: 28 September 1998

Fund Project: This work was supported by the science grant of Shandong province.

A complex of N.N'-ethylenebis (salicylidenciminato) diaquochromium(Ⅲ) chloride.[Cr (salen) (H₂O)₂] Cl was prepared, and its decomposition mechanism was studied by TG and DTA. The IR spectrum of the product of thermal decomposition was examined at the first stage Kinetic results were obtained from the analysis of TG-DTG curves with three different methods The most probable kinetic functions were suggested by comparison of kinetic parameters.
- Chromium(Ⅲ) complex,
- thermal decomposition,
- non-isothermal kinetics
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