Citation: Xue Yan SHI, Hong Chao GUO, Zhen QIAO, Shi Cong HOU, Min WANG. The Enantiomer Separations of Allethrone and Propargyllone Using Two Long Chain Acylated β-Cyclodextrin Derivatives as CGC Capillary Stationary Phases[J]. Chinese Chemical Letters, ;2002, 13(10): 973-976. shu

The Enantiomer Separations of Allethrone and Propargyllone Using Two Long Chain Acylated β-Cyclodextrin Derivatives as CGC Capillary Stationary Phases

Key Laboratory of Pesticide Chemistry and Application Technology, College of Applied Chemistry, China Agricultural University, Beijing 100094

Received Date: 28 December 2001

Using two β-cyclodextrin derivatives (CDs) with long chain of acyl groups as chiral stationary phases (CSPs) of capillary gas chromatography (CGC), the enantiomers of racemic allethrone and propargyllone were well resolved after derived with acetyl chloride. The enantiomer excess values (e.e.%) of 1S-allethrone and 1S-propargyllone were also determined successfully using these CDs.
- Enantiomer separation,
- allethrone,
- propargyllone,
- capillary gas chromatography (CGC),
- β-cyclodextrin derivatives
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