Citation: ZHANG Xiaoqing, QIU Lingshi, WANG Dongsheng, WANG Yuanshen. NMR STUDY ON THE COMPATIBILITY OF ACR/PVC BLENDS[J]. Chinese Journal of Polymer Science, ;1988, 6(2): 159-164. shu

NMR STUDY ON THE COMPATIBILITY OF ACR/PVC BLENDS

Received Date: 10 May 1987

A 300MHz solid NMR study on the compatibility of ACR (poly (methyl methacrylate-co-methacrylate), in the ratio of 1:1)-PVC (poly (vinyl chloride)) blends is reported. Spin-lattice (T1) and spin-spin (T2) relaxation time of ACR, PVC and their blends are recorded in the temperature range from 215K to 355K. Experimental results indicate that ACR and PVC are compatible with each other and the domain size is smaller than 25 nm, but heterogeneit(?)s of molecular dimensions still exist. Some problems of mechanism of compatibility and data analysis are also discussed.
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