Citation: QIU Kunyuan, SONG Ye. GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION[J]. Chinese Journal of Polymer Science, ;1988, 6(1): 75-83. shu

GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION

QIU Kunyuan ,
SONG Ye

Received Date: 11 February 1987

Functional monomers having phenylcarbamoyl and p-tolylcarbamoyl were synthesized. Binary initiation system consisted of Ce4+ and these functional monomers could initiate acrylamide polymerization. It was found that acrylamide could graft copolymerize onto macromolecules having these functional monomers units. The formation of graft copolymer has been verified by its percentage of water absorption, contact angle with water, XPS and SEM photographs. The reaction mechanism was proposed and the main reactive site of graft copolymerization by Ce4+ would take place predominantly at the functional pendant group.
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