Citation: Ji Xiang LIU, Qing Fu ZHOU, Hui Jun XU. PHOTOINDUCED INTRAMOLECULAR ELECTRON TRANSFER IN A NOVEL ZINC PHTHALOCYANINE-VIOLOGEN-FERROCENE TRIAD SYSTEM[J]. Chinese Chemical Letters, ;1993, 4(4): 339-342. shu

PHOTOINDUCED INTRAMOLECULAR ELECTRON TRANSFER IN A NOVEL ZINC PHTHALOCYANINE-VIOLOGEN-FERROCENE TRIAD SYSTEM

Institute of Photographic Chemistry, Academia Sinica, P.O.Box 772, Beijing 100101

Received Date: 15 October 1992

Fund Project: This work was supported by the National Advanced Material Committee of China. We thank Professor K. Tokumaru of Tsukuba University of Japan for transient absorption determinations.

A novel triad system zinc phthalocyanine-viologen-ferrocene has been synthesized.Photoinduced intramolecular electron transfer in the new triad system was investigated by fluorescence quenching experiment and nanosecond flash photolysis technique,giving a final long-living chargeseparated state.A mechanism of two-step charge separation was suggested.
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