Citation: Yang Jie WU, Xiu Ling CUI, Mao Ping SONG, Ning ZHOU, Chen Xia DU, Yu ZHU. Synthesis and Isolation of Diastereomers of Optically Active Cyclomercurated Ferrocenylimines[J]. Chinese Chemical Letters, ;2000, 11(11): 975-978. shu

Synthesis and Isolation of Diastereomers of Optically Active Cyclomercurated Ferrocenylimines

1.
Department of Chemistry, Zhengzhou University, Zhengzhou 450052;
2.
Henan Provincial Laboratory of Applied Chemistry, Zhengzhou University, Zhengzhou 450052

Received Date: 24 April 2000

Fund Project: We are grateful to the National Natural Science Foundation of China (Project 29572066) and the Natural Science Foundation of Henan Province for financial support of this work.

Asymmetric cyclomercuration of chiral ferrocenylimines (+)-(R)-2 and (-)-(S)-2 with mercuric acetate and subsequent treatment by lithium chloride gave a mixture of diastereomeric cyclomercurated ferrocenylimines. The four enantiomeric pure compounds with both planar and central chirality were isolated from the two mixtures by the thin layer chromatography.
- Chiral ferrocenylimines,
- asymmetric cyclomercuration
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