Citation: Jing Jiang LIU, Lian De LU. THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule[J]. Chinese Chemical Letters, ;1990, 1(1): 9-12. shu

THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule

Department of Chemistry Nankai University Tianjin 300071

Received Date: 20 November 1989

Fund Project: This work was supported by the National Natural Science Foundation of China. We are also grateful to Mrs. Fang Guo for help in the structure determination.

The electrostatic potential of carbene and nitrene, have been calculated by ABINITIO method with 6-31G** basis set, there are positive potential regions in the directionsof vacant P orbitals, and negative regions in the directions of lone-pair electrons.Therefore, atoms in these molecules have different electric properties in differentdirections.The idea of electrophilic and nucleophilic directions of an atom in moleculesshould be introduced.
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