Citation: FENG Pinzhen, WANG Aiwen. SYNTHESIS AND POLYMERIZATION OF 2-OXO-3-METHYLENE-1,4-DIOXANES[J]. Chinese Journal of Polymer Science, ;1991, 9(3): 220-225. shu

SYNTHESIS AND POLYMERIZATION OF 2-OXO-3-METHYLENE-1,4-DIOXANES

FENG Pinzhen ,
WANG Aiwen

Received Date: 22 June 1990

A new kind of monomers was successfully synthesized by the reaction between 2-chloro methyl cycloketal and trimethylsilyl cyanide, followed by ring closure and dehaiogenation. Polymerizations of the monomers were carried out in benzene solution at 80℃ with benzoyl peroxide as initiator. Both the structures of monomers and polymers were characterized by IR, 1H NMR, 13C NMR and elemental analysis.
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