Citation:
. SYNTHESIS AND CHARACTERIZATION OF SOLUBLE POLYPHENYLENE COMPOSED OF p-PHENYLENE AND m-PHENYLENE UNITS[J]. Chinese Journal of Polymer Science,
;2002, 20(4): 333-337.
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NiCl2(bpy) catalyzed polycondensation between p-dibromobenzene and m-dibromobenzene has been carried outunder vdrious conditions. The polycondensation endows the copolymer with an Mn of 2300 (by GPC, polystyrene standards)and good solubility in organic solvents. The fluorescence spectra of the copolymer measured with tetrahydrofuran solutionshows an emission maximum (λmax) at 372.8 nm, whereas for the film the maximum shifts to 436.6 nm.
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