Citation: Chun Nuan JI, Xiu Juan ZHANG, Rong Jun QU, Hou CHEN, Chun Hua WANG, Chang Mei SUN. Synthesis and Adsorption Properties of Chelating Resins Containing Sulfoxide and Heterocyclic Functional Groups[J]. Chinese Chemical Letters, ;2006, 17(10): 1313-1316. shu

Synthesis and Adsorption Properties of Chelating Resins Containing Sulfoxide and Heterocyclic Functional Groups

1.
School of Chemistry and Materials Science, Yantai Normal University, Yantai 264025;
2.
Elementary department, Yantai Vocational College, Yantai 264025

Received Date: 15 May 2006

Fund Project: The authors are grateful for the financial support by the Postdoctoral Science Foundation of China (No. 2003034330), the Science Foundation for mid-youth elite of Shandong Province, the Nature Science Foundation of Shandong Province (No. Y2005F11 and No. 2005BS11010), the Nature Science Foundation of Yantai Normal University (No. 032912, 20052901, 042920), Educational Project for Postgraduate of Yantai Normal University (No. YD05001), Applied Project of Educational Bureau of Shandong Province (No. J05D03, J04B02).

Several of new chelating resins containing sulfoxide and heterocyclic functional groups (3-aminopyridine and 2-mercaptobenzothiazole) based on macroporous chloromethylated polystyrene were synthesized and characterized by elemental analysis and infrared spectra. Their adsorption capacities towards Zn²⁺, Cu²⁺, Pb²⁺, Hg²⁺ and Ag⁺ at pH 3.0 and 6.0 were investigated in detail. It was found that the adsorption capacities of the resins containing bis[(3-pyridylaminoethyl)sulfoxide or (2-benzothiazolylthioethyl) sulfoxide for the above ions were higher than that on ones containing single above-mentioned groups.
- Chelating resins,
- heterocyclic functional groups,
- sulfoxide,
- distribution coefficient,metal ions
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