Citation: Xiao Yan SONG, Hai Ping GENG, Qi Fang LI. Synthesis and Characterization of Ferrocenyl Substituted Styryl Octasilsesquioxane[J]. Chinese Chemical Letters, ;2006, 17(4): 427-430. shu

Synthesis and Characterization of Ferrocenyl Substituted Styryl Octasilsesquioxane

College of material science and engineering, Beijing University of Chemical Technology, Beijing 100029

Received Date: 1 September 2005

Fund Project: We gratefully acknowledge the financial support of the National Natural Science Foundation of China (Project No. CN-20374007 and CN-50203002) and Key Project of Science and Technology Foundation of Ministry of Education (03023).

4-(2-Ferrocenylethenyl)-phenyl-POSS Fc-CH=CH-C₆H₆-(C₅H₉)₇Si₈O₁₂ (FEPS, Fc:ferrocene), containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemical structure of FEPS was characterized by FTIR, ¹H-, ¹³C and²⁹Si-NMR.
- Polyhedral silsesquioxane,
- ferrocene,
- Wittig reaction,
- synthesis
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