Citation: Zheng Ting CAI, Yu Guang MU. AN IMPROVED NONADIABATIC COLLISION MODEL FOR ION-PIR FORMATION PROCESS:A+BC → A⁺+BC^-[J]. Chinese Chemical Letters, ;1993, 4(3): 235-238. shu

AN IMPROVED NONADIABATIC COLLISION MODEL FOR ION-PIR FORMATION PROCESS:A+BC → A⁺+BC^-

Institute of Theoretical Chemistry Shandong University, Jinan 250100

Received Date: 17 August 1992

Fund Project: This work was supported by the National Natural Science Foundation of China.

Hickman's fast nonadiabatic collision model for the ion-pair formation reaction A+BC→A⁺+BC^-was improved,where the classical trajectory has been represented by solution of motion equation UR=-dV(R)/dR,here V(R)is Morse potential.Employing this model to the CS+O₂→CS⁺+O₂^-reaction,a satisfactory agreement with experimental data has been obtained.
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