Citation:
Zhe Feng FAN, Li Min DU. Determination of Phosphorus by Inductively Coupled Plasma Atomic Emission Spectroscopy after Hydride Generation[J]. Chinese Chemical Letters,
;2000, 11(5): 425-426.
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A continuous phosphine (PH3) generation was developed and applied to the sensitive detection of phosphorus by ICP-AES. Phosphate ion in aqueous solution was converted to phosphine by passing the sample solution through an incandescent copper silica-tube. Detection limit is 2 ng/mL. The relative standard deviation is 4.2% for 20 ng/mL. The method is rapid and simple with low contamination and high sensitivity.
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Keywords:
- Hydride generation,
- phosphate,
- ICP-AES
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