Citation: Cheng Guo JIA, Yun Pu WANG, Han Yu FENG. A LOW-PRESSURE AND ONE-STEP METHOD FOR THE SYNTHESIS OF ALKYLIDYNETRICOBALT NONACARBONYL CLUSTERS:RCCo₈（CO）₉[J]. Chinese Chemical Letters, ;1993, 4(2): 121-122. shu

A LOW-PRESSURE AND ONE-STEP METHOD FOR THE SYNTHESIS OF ALKYLIDYNETRICOBALT NONACARBONYL CLUSTERS:RCCo₈（CO）₉

Institute of Chemistry, Northwest Normal University, Lanzhou 730070

Received Date: 23 July 1992

Metal clusters RCCo_a（CO）₉（R-H,C1,Br,CH_a,Ph） were preparedin 18.8-57.3% yields from the reaction of cobalt(Ⅱ)salt and RCX_a under mild PTC conditions(latm CO,25℃).The cobalt salt was reducedto Co（CO）₄ in the presence of Na_aS₂O₄.
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