Citation: Zhan Mei LIU, Wei LIAN, Hai Xia SHI, Tong NIU, Xi Shan LIA. Synthesis and Characterization of Thermotropic Liquid Crystalline Complexes Containing Ferrocenyl Group[J]. Chinese Chemical Letters, ;1996, 7(11): 1039-1040.
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Four ferrocenyl long-chain alkyl β-diketonato zinc(Ⅱ)complexes with a general formula ZnL2(L=C5H5FeC5H4COCHCOCnH2n+1.n=6-9)were synthesized.These complexes were characterized by elementary analysis,IR.1HNMR MS、polarizing microscopy with a heating stage and DSC.It was found that the complexes have thermotropic liquid crystalline properties.The type of the heteronuclear liquid crystalline metal complexes have not been reported so far.
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