Citation: An Ming LIU, Lin HUANG, Yi De XU, Takafumi SHIDO, Macaru ICHIKAWA. SYNTHESIS AND CHARACTERIZATION OF ［Ru₆（CO）₁₈］^2-IN NaX ZEOLITE CAGES AND ITS CATALYTIC BEHAVIOR FOR n-C₄H₁₀HYDROGENOLYSIS[J]. Chinese Chemical Letters, ;1995, 6(2): 163-164. shu

SYNTHESIS AND CHARACTERIZATION OF ［Ru₆（CO）₁₈］^2-IN NaX ZEOLITE CAGES AND ITS CATALYTIC BEHAVIOR FOR n-C₄H₁₀HYDROGENOLYSIS

1.
State Key Laboratory for Catalysis, Dalian 116023;
2.
Catalysis Research Center. Hokkaido University, Sapporo 060, JAPAN

Received Date: 26 July 1994

Ru^Ⅲ(NH₃)₆in the cages of NaX zeolite was converted in the presence of CO+H₂into[Ru₆(CO)₁₈]^2-,which was characterized by in-situ FTIR,UV-VIS and EXAFS spectroscopies.The material derived from[Ru₆(CO)₁₈]^2-/NaX exhibited high catalytic activity in n-butane hydrogenolysis.
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