Citation: Chu Hua LI, Xiao Yi WEI, Xu E LI, Ping WU, Bao Jiang GUO. A New Anthranquinone Glycoside from the Seeds of Cassia obtusifolia[J]. Chinese Chemical Letters, ;2004, 15(12): 1448-1450. shu

A New Anthranquinone Glycoside from the Seeds of Cassia obtusifolia

Chu Hua LI ^1, ,
Xiao Yi WEI ² ,
Xu E LI ¹ ,
Ping WU ² ,
Bao Jiang GUO ¹

1.
College of Life Science, South China Normal University, Guangzhou 510631;
2.
South China Institute of Botany, Chinese Academy of Sciences, Guangzhou 510650

Received Date: 27 October 2003

Fund Project: The ID and 2D NMR spectra were measured by Dr. Jingsun Fan, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou. This investigation was supported by programs from Guangdong Provincial Department of Science and Technology (No. C30113) and Guangzhou Municipal Department of Science and Technology (No. 2000Z3-E5041).

A new anthraquinone glycoside, emodin-1-O-β-gentiobioside 1, together with three known compounds, chrysophanol-1-O-β-gentiobioside 2, physcion-8-O-β-gentiobioside 3, and chrysophanol-1-O-β-D-glucopyranosyl-(1→3)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside 4 was isolated from the seeds of Cassia obtusifolia. Its structure was elucidated on the basis of spectroscopic evidence.
- Cassia obtusifolia,
- Leguminosae,
- anthraquinone glycosides,
- emodin-1-O-β-gentiobioside
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8. [8]
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9. [9]
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