Citation: Yu Xia DIAO, Yang TIAN, Si Hui ZHAN, Wen Xing ZHANG, Xiu Ling JIAO, Dai Rong CHEN. Synthesis and Structure of Vanadium-barium Complex of 2,4,6-Tripicolinato with 20-Member Macrocyclic Cavities[J]. Chinese Chemical Letters, ;2003, 14(7): 740-743. shu

Synthesis and Structure of Vanadium-barium Complex of 2,4,6-Tripicolinato with 20-Member Macrocyclic Cavities

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100

Received Date: 26 August 2002

Fund Project: This project is supported by NNSF of China (60172003) and Specialized Research Foundations of Shandong Province (11120106).

A new heteronuclear complex, dimer[(μ₂-OH₂)₂Ba₂(H₂O)₄] [VO₂(tpa)]₂·4H₂O(tpa:2,4,6-tripicolinate trianion), was synthesized and structurally determined by X-ray diffraction technique where all hydrogen atoms have been located directly. The coordination geometry of V(V) ion is a distorted trigonal bipyrimid and that of Ba(Ⅱ) ion is a capped square antiprism. One μ₂-O bridging bond and two hydrogen bonds act between the coordination geometries. A 1-D extended porous construction containing 20-member cavities is observed in the crystal.
- Heteronuclear,
- vanadium-barium complex,
- synthesis,
- cavity,
- structure
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