Citation: Wei Jiang HE, Fang LIU, Zhi Feng YE, Zi Jian GUO, Jun Bai LI, Long Gen ZHU. A New Strategy for Architecture of Robust Monolayer Based on Binuclear Palladium (Ⅱ) Complex of Calix[4]arene Derivative[J]. Chinese Chemical Letters, ;2000, 11(11): 1027-1030. shu

A New Strategy for Architecture of Robust Monolayer Based on Binuclear Palladium (Ⅱ) Complex of Calix[4]arene Derivative

1.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;
2.
Laboratory of Colloid and Interface Science, Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080

Received Date: 8 May 2000

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 29771019, 29871017 and 29823001). The authors also thank Prof. Ming Hua LIU for his kind help in this study.

A monolayer which is formed by a binuclear palladium complex of low rim methioninedisubstituted calix[4]arene exhibits extraordinary cohesiveness. Cohesiveness measurement and Brewster Angle Microscopy observation show that the monolayer is uniform and robust. This film is probably formed by self-assembly of precursor complex through strong chloride ion bridge between palladium centers.
- Monolayer,
- calix[4]arene,
- Brewster Angle Microscopy,
- robust membrane,
- viscosity
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