Citation: Dong Lin JIANG, Yi Feng ZHANG, Hong Jie FU, Zhi Quan SHEN. SYNTHESES OF METHYL-AND ETHYL-VINYL SULFOXIDES AND THEIR APPLICATIONS TO MEMBRANE MATERIALS FOR GAS SEPARATION[J]. Chinese Chemical Letters, ;1992, 3(2): 79-82. shu

SYNTHESES OF METHYL-AND ETHYL-VINYL SULFOXIDES AND THEIR APPLICATIONS TO MEMBRANE MATERIALS FOR GAS SEPARATION

Department of Chemistry, Zhejiang University, Hangzhou, 310027

Received Date: 25 September 1991

Fund Project: Project supported by National Education Commission of China and Science and Technologv Commission of Zhejiang Province.

Methyl-and Ethyl-vinyl sulfoxides (MVSO and EVSO) were first synthesized from common organic reagents, i.e. sulfate, thiourea and ethylene oxide in excellent yields. A new facile method for oxidation of vinyl sulfides to corresponing vinyl sulfoxides was developed. Application of those vinyl sulfoxides for synthetic gas separation membranes was acheived and that showed the high permselectivities to SO₂, N₂ and SO₂/N₂ mixture gases.
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