Citation: Rong Min WANG, Xiao Dong LI, Yu Feng HE. Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen[J]. Chinese Chemical Letters, ;2006, 17(2): 265-268. shu

Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen

Gansu Key Laboratory of Polymer Materials, Northwest Normal University, Lanzhou 730070

Received Date: 13 June 2005

Fund Project: The project was supported by the National Natural Science Foundation of China (No.20274034).

A new stable salen Schiff base cobalt and crown ether sodium complex (SalCo-NaB18C6) was prepared through copolymerization. This copolymer complex was applied to catalytic oxidation of hydrocarbon compound with molecular oxygen without reductant, which was shown the higher activity and selectivity for ketone, and reused effectively.
- Copolymeric complexes,
- cyclohexene,
- catalysis,
- salen Schiff base,
- crown ether
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